It works, at least when you're saving and loading to and from the Documents-Directory of your running app.
//Creating Path to Documents-Directory
NSArray *paths = NSSearchPathForDirectoriesInDomains(NSDocumentDirectory, NSUserDomainMask, YES);
NSString *documentsDirectory = [paths objectAtIndex:0];
NSString *filePath = [documentsDirectory stringByAppendingPathComponent:[NSString stringWithFormat:@"ocv%03d.BMP", picNum]];
const char* cPath = [filePath cStringUsingEncoding:NSMacOSRomanStringEncoding];
const cv::string newPaths = (const cv::string)cPath;
//Save as Bitmap to Documents-Directory
cv::imwrite(newPaths, frame);