Some IDEs specialised in XML will do that for you.
Here are the most well known
- oXygen
- Stylus Studio
- xmlSpy
For instance in oXygen, you can right-click on an element part of an XML document and the contextual menu will have an option 'Copy Xpath'.
There are also a number of Firefox add-ons (such as XPather that will happily do the job for you. For Xpather, you just click on a part of the web page and select in the contextual menu 'show in XPather' and you're done.
But, as Dan has pointed out in his answer, the XPath expression will be of limited use. It will not include predicates for instance. Rather it will look like this.
/root/nodeB[2]/subnodeX[2]
For a document like
<root>
<nodeA>stuff</nodeA>
<nodeB>more stuff</nodeB>
<nodeB cond="thisOne">
<subnodeX>useless stuff</subnodeX>
<subnodeX id="MyCondition">THE STUFF YOU WANT</subnodeX>
<subnodeX>more useless stuff</subnodeX>
</nodeB>
</root>
The tools I listed will not generate
/root/nodeB[@cond='thisOne']/subnodeX[@id='MyCondition']
For instance for an html page, you'll end-up with the pretty useless expression :
/html/body/div[6]/p[3]
And that's to be expected. If they had to generate predicates, how would they know which condition is relevant ? There are zillions of possibilities.