If your grep doesn't support -P or --perl-regexp, and you can install PCRE-enabled grep, e.g. "pcregrep", than it won't need any command-line options like GNU grep to accept Perl-compatible regular expressions, you just run
pcregrep "Ui\.(?!Line)"
You don't need another nested group for "Line" as in your example "Ui.(?!(Line))" -- the outer group is sufficient, like I've shown above.
Let me give you another example of looking negative assertions: when you have list of lines, returned by "ipset", each line showing number of packets in a middle of the line, and you don't need lines with zero packets, you just run:
ipset list | pcregrep "packets(?! 0 )"
If you like perl-compatible regular expressions and have perl but don't have pcregrep or your grep doesn't support --perl-regexp, you can you one-line perl scripts that work the same way like grep:
perl -e "while (<>) {if (/Ui\.(?!Lines)/){print;};}"
Perl accepts stdin the same way like grep, e.g.
ipset list | perl -e "while (<>) {if (/packets(?! 0 )/){print;};}"