I've been evaluating it lately for a client so I've had some time with it. My impression at this point is that it is just finishing "growing up" from being an academic experimental playground. It clearly has yet to be really discovered, though it does have some rough edges which might hinder certain applications.
As I write, I'm in the process of trying to load over 100 million rows into an instance (at 27mil presently). So far, it performs startlingly well in some areas (aggregates), but is oddly sluggish in others (most joins I've tried so far); that said, I've not yet run the recommended sampling process yet and I'm forcing it to live in just a single service with 32GB RAM.
I've found a few little glitches and one thing that caused a full service crash (obscure and reported), but I'm thinking that for many applications MonetDB could be just the ticket. Columnar storage (rather than NoSQL) seems to be the future IMO.
I'll update this if I find anything particularly interesting.