I'd have to assume that "addthis" is an XML namespace; does the html tag declare something like <html xmlns:addthis="..">
? If not, it won't validate because the namespace is undefined for the document. If so, it won't validate because "addthis" isn't a standard namespace.
See: http://www.w3.org/TR/2011/WD-html5-20110405/namespaces.html
Confounded to your troubles is the fact that "the HTML syntax does not support namespace declarations, even in foreign elements."
Check out http://www.w3.org/TR/2011/WD-html5-20110405/syntax.html#elements-0 , the cdr:license
example.
Unfortunately (in your case) HTML5 isn't XML, so XML namespaces aren't necessarily valid in HTML5. Your only real option is to ignore the validation error.
Not unrelated question: HTML5 validator failing on Facebook OpenGraph XML Namespace xmlns:og
Oh, and while you're there, the <tag />
syntax is also XML, not HTML5.