I think this link can be useful for you.
Here you have samples how to read / parse, modify (add elements) and save (write to xml file again).
The following samples you can find at: http://www.petefreitag.com/item/445.cfm
Read:
DocumentBuilderFactory docFactory = DocumentBuilderFactory.newInstance();
DocumentBuilder docBuilder = docFactory.newDocumentBuilder();
Document doc = docBuilder.parse("/path/to/file.xml");
Modify:
// attributes
Node earth = doc.getFirstChild();
NamedNodeMap earthAttributes = earth.getAttributes();
Attr galaxy = doc.createAttribute("galaxy");
galaxy.setValue("milky way");
earthAttributes.setNamedItem(galaxy);
// nodes
Node canada = doc.createElement("country");
canada.setTextContent("ca");
earth.appendChild(canada);
Write XML file:
Transformer transformer = TransformerFactory.newInstance().newTransformer();
transformer.setOutputProperty(OutputKeys.INDENT, "yes");
//initialize StreamResult with File object to save to file
StreamResult result = new StreamResult(new StringWriter());
DOMSource source = new DOMSource(doc);
transformer.transform(source, result);
String xmlString = result.getWriter().toString();
System.out.println(xmlString);