First, I'll answer the question that you actually asked:
System.DirectoryServices.ActiveDirectory.ActiveDirectorySite.GetComputerSite().Servers
But it seems like you're asking how to make sure that you're talking to the closest domain controller possible. Windows doesn't exactly provide this functionality, the best it will do is give you a domain controller in the same site that the code is running from.
I think the first thing to check is that you have your sites and subnets configured correctly. Run Active Directory Sites and Services, and make sure that subnets and domain controllers are assigned to the correct sites.
This MSDN page (and the Technet article in Peter's answer) says that you must be searching by the DNS name for the DC Locator to attempt to find a DC in the current site. I don't know if the Name property of the Domain class is the DNS domain name.
I have to assume that DomainController.FindOne is a wrapper for DsGetDcName
. At that link, you can find how to turn on tracing for that function. You can use this if you still have problems, or maybe you should just PInvoke this function.