You need to run the form server side:
<form id="Form1" runat="server> ... </form>
However, if you are using ASP.NET Web Forms you can only have 1 form per web form running server side.
EDIT: After seeing your edit, I would recommend posting the values to a standalone value on your website using Response.Redirect()
:
Response.Redirect("GoogleCheckout.aspx?field=" + fieldvalue);
Then on this standalone page have the following:
<form action="https://sandbox.google.com/checkout/..." id="Form1" method="post" name="..." target="_top">
<input name="item_name_1" type="hidden" value="<%= Request.Querystring["field"] %>" />
...
<input alt="" src="https://sandbox.google.com/checkout/buttons/buy.gif?merchant_id=..." type="image" />
</form>
Then use javascript/jquery to automatically post this form onload:
$("form").submit();
This gets around the issue of only having 1 form per page.