I really see no reason to use any external libraries for this, I've done this sort of thing many times and the following algorithm works quite well. I'll assume that if you're comparing two images that they have the same dimensions, but you can just resize one if they don't.
badness := 0.0
For x, y over the entire image:
r, g, b := color at x,y in image 1
R, G, B := color at x,y in image 2
badness += (r-R)*(r-R) + (g-G)*(g-G) + (b-B)*(b-B)
badness /= (image width) * (image height)
Now you've got a normalized badness value between two images, the lower the badness, the more likely that the images match. This is simple and effective, there are a variety of things that make it work better or faster in certain cases but you probably don't need anything like that. You don't even really need to normalize the badness, but this way you can just come up with a single threshold for it if you want to look at several possible matches manually.
Since this question has gotten some more attention I've decided to add a way to speed this up in cases where you are processing many images many times. I used this approach when I had several tens of thousands of images that I needed to compare, and I was sure that a typical pair of images would be wildly different. I also knew that all of my images would be exactly the same dimensions. In a situation in which you are comparing dialog boxes your typical images may be mostly grey-ish, and some of your images may require resizing (although maybe that just indicates a mis-match), in which case this approach may not gain you as much.
The idea is to form a quad-tree where each node represents the average RGB values of the region that node represents. So an 4x4 image would have a root node with RGB values equal to the average RGB value of the image, its children would have RGB values representing the average RGB value of their respective 2x2 regions, and their children would represent individual pixels. (In practice it is a good idea to not go deeper than a region of about 16x16, at that point you should just start comparing individual pixels.)
Before you start comparing images you will also need to decide on a badness threshold. You won't calculate badnesses above this threshold with any reliable accuracy, so this is basically the threshold at which you are willing to label an image as 'not a match'.
Now when you compare image A to image B, first compare the root nodes of their quad-tree representations. Calculate the badness just as you would for a single pixel image, and if the badness exceeds your threshold then return immediately and report the badness at this level. Because you are using normalized badnesses, and since badnesses are calculated using squared differences, the badness at any particular level will be equal to or less than the badness at lower levels, so if it exceeds the threshold at any points you know it will also exceed the threshold at the level of individual pixels.
If the threshold test passes on an nxn image, just drop to the next level down and compare it like it was a 2nx2n image. Once you get low enough just compare the individual pixels. Depending on your corpus of images this may allow you to skip lots of comparisons.