A quick bit of googling got me to this page, which includes a function for calculating the number of working days between two dates.
It should be fairly trivial to adjust that concept to suit your needs.
Your problem, however, is that the concept of "working days" being monday to friday is not universal. If your software is only ever being used in-house, then it's okay to make some assumptions, but if it's intended for use by third parties, then you can't assume that they'll have the same working week as you.
In addition, public holidays will throw a big spanner in the works, by removing arbitrary dates from various working weeks throughout the year.
If you want to cater for these, then the only sensible way of doing it is to store the dates of the year in a calendar (ie a big array), and mark them individually as working or non-working days. And if you're going to do that, then you may as well use the same mechanism for weekends too.
The down-side, of course, is that this would need to be kept up-to-date. But for weekends, at least, that would be trivial (loop through the calendar in advance and mark weekend days where date('w')==0 or date('w')==6
).