This usually happens when you have Target framework = .NET Framework Client Profile, but DLL you reference is from .NET Framework (full). Make sure you have System.dll in your references from valid framework.
I just did the same - created empty console application with the following code:
using System;
using System.Collections.Generic;
using System.Diagnostics;
using System.ComponentModel;
using System.Linq;
using System.Text;
namespace ConsoleApplication1
{
class Program
{
static void Main(string[] args)
{
var prc = Process.Start("explorer.exe");
}
}
}
Works perfectly fine for me.
Additional thing to check is Intellisense - when you start typing "System.Diagnostics.Proc"... - does it show you dropdown with "Process" there?
UPDATE:
Windows Store projects are based on different version of target .NET Framework - .NET for Windows Store apps, which does not support functionality you need.
For more details do web search:".NET for Windows Store apps". Helpful links:
http://msdn.microsoft.com/en-us/library/windows/apps/br230302.aspx
http://msdn.microsoft.com/en-us/library/windows/apps/br230232.aspx