What I want is perhaps too simple, and I'm a bit overwhelmed by the responses I find!
***I'd prefer a pure CSS/HTML solution as I don't use javascript.***
What I'm doing at the moment is to use the TITLE attribute within an anchor tag to display information about the link (see: http://www.helpdesk.net.au/index_safety_driver.html and mouseover some of the links).
What I'd like to do is to have something a bit more flexible and interesting for that content and so I'm looking at floating a DIV over a link on hover instead of TITLE (can I leave TITLE in in case the DIV isn't supported - as a failsafe?).
I like the concept at http://www.barelyfitz.com/screencast/html-training/css/positioning/ but would like to have the option of an image in the top left corner.