The RELATED
property does exactly that (see RFC 6350 p.43). Quoting the specs, the purpose of this property is:
To specify a relationship between another entity and the entity
represented by this vCard.
Its value can be either a URI or free-form text. Examples of useful URIs include website addresses, URLs pointing to a vCard, or URNs that reference the UID
property of another vCard.
It also has a TYPE
parameter, which can optionally be used to define the type of relationship. The list of acceptable values for this parameter can be found in the vCard specs.
RELATED;TYPE=parent:http://example.com/jeb-doe.vcf
RELATED;TYPE=sibling:urn:uuid:f81d4fae-7dec-11d0-a765-00a0c91e6bf6
RELATED;TYPE=spouse;VALUE=text:Jane Doe
RELATED
is supported in vCard version 4.0.