The problem is the table violates first normal form, EmpLotusNotes should not contain the name of an employee and the country, presumably the country they work in.
You should challenge the reasons why you are not allowed to clean up the structure and the data.
See https://www.google.com.au/search?q=sql+first+normal+form+atomic
The answer, if you still cannot normalise the database after challenging, is create a query for countries, create a query to split the data in the first table into first normal form, then join the two.
An example that works for mysql follows, for MS SQL you would use CHARINDEX instead of INSTR and substring instead of substr.
select employeesWithCountries.*
, countries.sort
from (
select empId, empLotusNotes, substr( empLotusNotes, afterStartOfDelimiter ) country from (
select empId
, empLotusNotes
, INSTR( empLotusNotes, '/' ) + 1 as afterStartOfDelimiter
from EmployeesLotusNotes
) employees
) employeesWithCountries
inner join (
SELECT 'Japan' as country, 1 as sort
union
SELECT 'China' as country, 2 as sort
union
SELECT 'India' as country, 3 as sort
union
SELECT 'USA' as country, 4 as sort
) countries
on employeesWithCountries.country = countries.country
order by countries.sort, employeesWithCountries.empLotusNotes
Results.
30003 Kyo Jun/Japan Japan 1
40004 Jee Lee/China China 2
10001 Amit B/India India 3
20002 Bharat C/India India 3
50005 Xavier K/USA USA 4