In java it would be easiest to pre-format your input and just ask for constants--as in, "Please enter the X^2 term" (and then the X term, and then the constant).
If that's not acceptable, you are going to be quite vulnerable to input style differences. You can separate the terms by String.split[ting] on + and -, that will leave you something like:
[5x^2], [7x], [10]
You could then search for strings containing "x^2" and "x" to differentiate your terms
Remove spaces and .toLowerCase() first to counter user variances, of course.
When you split your string you will need to identify the - cases so you can negate those constants.
You could do two splits, one on + the other on -. You could also use StringTokenizer with the option to keep the "Tokens" which might be more straight-forward but StringTokenizer makes some people a little uncomfortable, so go with whatever works for you.
Note that this will succeed even if the user types "5x^2 + 10 + 7 x", which can be handy.