The other answers cover how to do std dev in python sufficiently, but no one explains how to do the bizarre traversal you've described.
I'm going to assume A-Z is the entire population. If not see Ome's answer on how to inference from a sample.
So to get the standard deviation/mean of the first digit of every list you would need something like this:
#standard deviation
numpy.std([A_rank[0], B_rank[0], C_rank[0], ..., Z_rank[0]])
#mean
numpy.mean([A_rank[0], B_rank[0], C_rank[0], ..., Z_rank[0]])
To shorten the code and generalize this to any nth digit use the following function I generated for you:
def getAllNthRanks(n):
return [A_rank[n], B_rank[n], C_rank[n], D_rank[n], E_rank[n], F_rank[n], G_rank[n], H_rank[n], I_rank[n], J_rank[n], K_rank[n], L_rank[n], M_rank[n], N_rank[n], O_rank[n], P_rank[n], Q_rank[n], R_rank[n], S_rank[n], T_rank[n], U_rank[n], V_rank[n], W_rank[n], X_rank[n], Y_rank[n], Z_rank[n]]
Now you can simply get the stdd and mean of all the nth places from A-Z like this:
#standard deviation
numpy.std(getAllNthRanks(n))
#mean
numpy.mean(getAllNthRanks(n))