I am here just to post my answer as I found it with the above comments.
I had no certificate chain, so in the work I'm doing I only have a certificate generated by me programatically. I wanted to check the validity of it, so I created the following function, which checks the certificate against itself in other to verify the validity of it.
void check_certificate_validaty(X509* certificate)
{
int status;
X509_STORE_CTX *ctx;
ctx = X509_STORE_CTX_new();
X509_STORE *store = X509_STORE_new();
X509_STORE_add_cert(store, certificate);
X509_STORE_CTX_init(ctx, store, certificate, NULL);
status = X509_verify_cert(ctx);
if(status == 1)
{
printf("Certificate verified ok\n");
}else
{
printf("%s\n", X509_verify_cert_error_string(ctx->error));
}
}
Hope this helps someone :)