Let's define what these terms mean in the first place:
- A "superkey" is any set of attributes that, when taken together, uniquely identify rows in the table.
- A minimal1 superkey is called "candidate key", or just "key".
- All keys in the same table are logically equivalent, but for historical and practical reasons we choose one of them and call it "primary", while the remaining are "alternate" keys.
So, every primary key is key, but not every key is primary. Every key is superkey, but not every superkey is key.
Constraints that physically enforce keys in the database are: PRIMARY KEY constraint (for primary key) and UNIQUE constraint (for alternate key). These constraints should not be created on all superkeys, only on keys.
It is not unusual to have multiple keys in the same table, depending on the nature of your data. For example, a USER table might have unique USER_ID and unique USER_NAME. Since both of them need to be unique on their own, you must create2 both keys, even though only one of them is strictly needed for identification.
1 That is, a superkey that would stop being unique (and therefore, being a superkey) if any of the attributes were removed from it.
2 I.e. create PRIMARY KEY or UNIQUE constraint.