If you use a Context lookup, you'll have to declare a new resource reference in the deployment descriptor (web.xml) :
<resource-ref>
<res-ref-name>jdbc/newReference</res-ref-name>
<res-type>javax.sql.DataSource</res-type>
<res-auth>Container</res-auth>
<res-sharing-scope>Shareable</res-sharing-scope>
</resource-ref>
But that's not all. You'll also have to bind this new reference to the server's JDBC resource (ibm-web-bnd.xml) :
<resource-ref name="jdbc/newReference" binding-name="jdbc/ressourceOnServer"/>
Note that this mechanism is quite similar to what is done on Glassfish with the sun-web.xml file, except that the binding is a little different :
<resource-ref>
<res-ref-name>jdbc/newReference</res-ref-name>
<jndi-name>jdbc/ressourceOnServer</jndi-name>
</resource-ref>
Look at this question : How do I connect to a Websphere Datasource with a given JNDI name?. If you need more details, I may give an example.