The word PASSWORD is a reserved keyword.
To use it you should enclose the string in square brackets
OleDbCommand cmd = new OleDbCommand("Insert into Info (username, [password]) Values ('" + username + "', '" + password + "')", conn);
And please, please, do not use string concatenation to build sql statements. It is a very bad practice that leads to other syntax errors (username or password with single quotes) or worst to a sql injection Attacks. Take a look here to what could happen if you have a smart and malicious user
OleDbCommand cmd = new OleDbCommand("Insert into Info (username, [password]) Values (?,?)", conn);
cmd.Parameters.AddWithValue("@p1", username);
cmd.Parameters.AddWithValue("@p2", password);
cmd.ExecuteNonQuery();