Here, the term O(1) means "some term that is O(1)," meaning some term that as n goes to infinity is bounded from above by some constant. For example, it might be 137, or sin n, or 1 / n2. The value described therefore might be ln ln n / ln 2 + 137, or ln ln n / ln 2 + sin n, etc.
This use of big-O notation is common in formal mathematics when discussing low order terms in a formula that contribute a small amount to the overall total. The authors could have also written that the entire expression is O(ln ln n), but this is less precise than ln ln n / ln 2 + O(1) because it obscures the fact that the coefficient on the ln ln n is 1 / ln 2 and that the only low-order growth term is bounded from above by a constant. By explicitly writing out " + O(1)", the authors are able to give much better precision.
Hope this helps!