You could make actual Objects, possibly with a Struct:
MyClass = Struct.new :a, :b
arr = [MyClass.new(1, 2), MyClass.new(3, 4)]
arr.map(&:a).reduce(:+) #=> 4
Or for more flexibility, an OpenStruct:
require 'ostruct'
arr = [OpenStruct.new(a: 1, b: 2), OpenStruct.new(a: 3, b: 4)]
arr.map(&:a).reduce(:+) #=> 4
Of course either of these can be constructed from existing hashes:
arr = [{ :a => 1, :b => 2 }, { :a => 3, :b => 4 }]
ss = arr.map { |h| h.values_at :a, :b }.map { |attrs| MyClass.new(*attrs) }
ss.map(&:a).reduce(:+) #=> 4
oss = arr.map { |attrs| OpenStruct.new attrs }
oss.map(&:a).reduce(:+) #=> 4
Or, for a more creative, functional approach:
def hash_accessor attr; ->(hash) { hash[attr] }; end
arr = [{ :a => 1, :b => 2 }, { :a => 3, :b => 4 }]
arr.map(&hash_accessor(:a)).reduce(:+) #=> 4