You can use NetworkCredential.Domain Property
The following code example uses the Domain property to set the domain associated with the credentials
// Create an empty instance of the NetworkCredential class.
NetworkCredential myCredentials = new NetworkCredential("", "", "");
myCredentials.Domain = domain;
myCredentials.UserName = username;
myCredentials.Password = password;
// Create a WebRequest with the specified URL.
WebRequest myWebRequest = WebRequest.Create(url);
myWebRequest.Credentials = myCredentials;
Console.WriteLine("\n\nUser Credentials:- Domain: {0} , UserName: {1} , Password: {2}",
myCredentials.Domain, myCredentials.UserName, myCredentials.Password);
// Send the request and wait for a response.
Console.WriteLine("\n\nRequest to Url is sent.Waiting for response...Please wait ...");
WebResponse myWebResponse = myWebRequest.GetResponse();
// Process the response.
Console.WriteLine("\nResponse received sucessfully");
// Release the resources of the response object.
myWebResponse.Close();
Here is the MSDN Link for more reading
Hope it will help