From Special Parameters in Bash Reference Manual
*
Expands to the positional parameters, starting from one. When the
expansion occurs within double quotes, it expands to a single word
with the value of each parameter separated by the first character of
the IFS special variable. That is, "$*" is equivalent to "$1c$2c…",
where c is the first character of the value of the IFS variable. If
IFS is unset, the parameters are separated by spaces. If IFS is null,
the parameters are joined without intervening separators.
@
Expands to the positional parameters, starting from one. When the
expansion occurs within double quotes, each parameter expands to a
separate word. That is, "$@" is equivalent to "$1" "$2" …. If the
double-quoted expansion occurs within a word, the expansion of the
first parameter is joined with the beginning part of the original
word, and the expansion of the last parameter is joined with the last
part of the original word. When there are no positional parameters,
"$@" and $@ expand to nothing (i.e., they are removed).
Better with an example:
$ d=(a b c)
$ for i in "${d[*]}"; do echo $i; done <---- it is a field all together
a b c
$ for i in "${d[@]}"; do echo $i; done <---- each item is a different field
a
b
c