In Windows 10 this worked for me. For starters please note that I had both Python 3 and Python 2 installed in my computer prior to encountering this error
Step 1
Go to folder C:\Users\USER\AppData\Local\Programs\Python\Python3X-XX and rename your Python.exe to Python3.exe (The 3X-XX represent whichever Python3 version you have installed & the Users\USER would be your computer's user account)
Step 2
Go to folder C:\Users\USER\AppData\Local\Programs\Python\Python3X-XX\Scripts and rename your pip.exe to pip3X.exe (use the same 3X which you have in the path)
Step 3
Go to your Python 2 folder (mine was at C:\Python27) and make sure that you have a exe file called python.exe
Step 4
Now go to your Environment Variables (Lower Right Button) under System Properties > Advance Tab. Once inside, double click the path under the System variables section. This will open up the list of paths that are in your system. Add both Python paths by clicking new and then browse (selecting first (C:\Python27) or whatever you Python 2 path is) and then by adding the Python 3 Path (C:\Users\USER\AppData\Local\Programs\Python\Python3X-XX).
Hit Ok on all screens and try running CQLSH or CQLSH 192.168.... (whatever the IP is of your seed node) via cmd and it should work!