Well if you get the query as an associative array, you can do something like this:
$query = "Select [stuff]";
$results = mysql_query($query);
$i = 0;
while ($row = mysql_fetch_assoc($results)) {
if ($i < 1) {
foreach($row as $key => $val) {
echo $key;//column name
}
}
//Do other stuff
$i++;
}
And yes, I know they should be doing mysqli_..., but this is my example using old mysql_...
Edit
To expand on this:
$query = "Select [stuff]";
$results = mysql_query($query);
$i = 0;
echo "<table>";
while ($row = mysql_fetch_assoc($results)) {
echo "<tr>";
if ($i < 1) {
foreach($row as $key => $val) {
echo "<td>".$key."</td>";//column name
}
}
echo "</tr>";
echo "<tr>";
foreach($row as $key => $val) {
echo "<td>".$val."</td>";//column name
}
echo "</tr>";
//Do other stuff
$i++;
}