a REST web service doesn't have any auto explanation document like wsdl, you need to know how the webservice works, reading the documentation provided with it. Generally it works with common requests. Assuming that you have a products REST webservice, you could have:
GET /products -> read all products
GET /products/1 -> read the product 1
POST /products -> create a new product
PUT /products/1 -> update product 1
DELETE /products/1 -> delete product 1
but you have to know which parameters you need to send to any request. I hope I was clear...