Try this
<?php
$string = '<div id="breadcrumbs">
<a href="/">Home</a>
<a href="/suppliers">Suppliers</a>
<a href="/suppliers/jewellers">This One i needed</a>
<span class="currentpage">Amrapali</span>
</div>';
//$matches[0] will have all the <a> tags
preg_match_all("/<a.+>.+<\/a>/i", $string, $matches);
//Now we remove the <a> tags and store the tag content into an array called $result
foreach($matches[0] as $key => $value){
$find = array("/<a\shref=\".+\">/", "/<\/a>/");
$replace = array("", "");
$result[] = preg_replace($find, $replace, $value);
}
//Make the last item in the $result array become the first
$result = array_reverse($result);
$last_item = $result[0];
echo $last_item;
?>