There is no correct straight-forward approach with any type of "Unicode string".
Even Python "Unicode" UTF-16 string has variable length characters so, you can't just cut with ustring[:5]. Because some Unicode Code points may use more then one "character" i.e. Surrogate pairs.
So if you want to cut 5 code points (note these are not characters) so you may analyze the text, see http://en.wikipedia.org/wiki/UTF-8 and http://en.wikipedia.org/wiki/UTF-16 definitions. So you need to use some bit masks to figure out boundaries.
Also you still do not get characters. Because for example. Word "שָלוֹם" -- peace in Hebrew "Shalom" consists of 4 characters and 6 code points letter "shin", vowel "a" letter "lamed", letter "vav" and vowel "o" and final letter "mem".
So character is not code point.
Same for most western languages where a letter with diacritics may be represented as two code points. Search for example for "unicode normalization".
So... If you really need 5 first characters you have to use tools like ICU library. For example there is ICU library for Python that provides characters boundary iterator.