If you will know at the start of runtime how many keys you'll enter, you can have it ask first for the number of keys and then for the individual characters, as in the untested snippet below.
Otherwise, you have to set some real-world maximum (e.g. 10000) that will never be reached, or, if that's not possible, set a per-array maximum and make provisions for rollover into a new array. That last option really is the same (eventually bounded by memory) but gives you a larger maximum.
char *mychars;
int numchars;
printf("Please enter the total number of characters:\n");
if (scanf("%d", &numchars) == NULL) {
printf("couldn't read the input; exiting\n");
exit(EXIT_FAILURE);
}
if (numchars <= 0) {
printf("this input must be positive; exiting\n");
exit(EXIT_FAILURE);
}
mychars = (char *) malloc (numchars * sizeof(char));
int current_pos = 0;
printf("Enter a digit and hit return:\n");
while (scanf("%c", &mychars[current_pos]) != NULL && current_pos < numchars) {
current_pos++;
printf("Enter a digit and hit return:\n");
}