My production code for username and password validation before sending mail:
public static bool ValidateCredentials(string login, string password, string server, int port, bool enableSsl) {
SmtpConnectorBase connector;
if (enableSsl) {
connector = new SmtpConnectorWithSsl(server, port);
} else {
connector = new SmtpConnectorWithoutSsl(server, port);
}
if (!connector.CheckResponse(220)) {
return false;
}
connector.SendData($"HELO {Dns.GetHostName()}{SmtpConnectorBase.EOF}");
if (!connector.CheckResponse(250)) {
return false;
}
connector.SendData($"AUTH LOGIN{SmtpConnectorBase.EOF}");
if (!connector.CheckResponse(334)) {
return false;
}
connector.SendData(Convert.ToBase64String(Encoding.UTF8.GetBytes($"{login}")) + SmtpConnectorBase.EOF);
if (!connector.CheckResponse(334)) {
return false;
}
connector.SendData(Convert.ToBase64String(Encoding.UTF8.GetBytes($"{password}")) + SmtpConnectorBase.EOF);
if (!connector.CheckResponse(235)) {
return false;
}
return true;
}
More details in the answer to a similar question.
Code on github