See the cURL documentation here:
http://curl.haxx.se/libcurl/c/CURLOPT_INTERFACE.html
Pass a char * as parameter. This sets the interface name to use as outgoing network interface. The name can be an interface name, an IP address, or a host name.
You can use this if your webserver has multiple network interfaces/ip addresses and you must select a specific interface for your request (eg your default gateway might be on your primary network interface but you need a request to go over a secondary interface).
EG You may have a request that needs to traverse a VPN.