Theres a couple of things going on here, and I'm not 100% of the result you want to accomplish, but we are working with CSS heights here so you need to keep some things in mind.
First of: when working with css heights, you need to make sure that all wrapping elements get the height of 100%. Including your body AND html tags. Without this, your body will just have the height of the elements inside it, and your 100% divs will do it to.
Second, you should turn of the body 'overflow: hidden' attribute, as it just obstructs correct testing.
Now, like I said, I'm not sure what you're trying to accomplish, but your header should be taken out of the wrapper as it is fixed. This will allow your wrapper to become the scrollable area. You also mentioned you wanted the second div to be 100% heigh and the first one 75%. Now, with position fixed this would mean your yellow div is only 75% visible, with 25% hidden (either by being off screen or under the header). If you want the first div and header together to take up 100%, and any subsequent div to take up 100% on their own, you should position all elements relative and not fixed.
I'm going to add some code here to help with a fixed header:
div#page-wrap {
height: 75%;
position: absolute;
top: 25%;
width: 100%;
overflow: scroll;
overflow-x: hidden;
}
about,
#aboutmore {
height: 100%;
position: relative;
top: 0%;
}
Now this will break your javascript (as you can't actually scroll the body), although I couldn't get it working in the first place anyhow. You'll find more about scrolling inside a div (as now you need to scroll in your wrapper element) in this thread: How do I scroll to an element within an overflowed Div?