A primary key can also be a combination of multilple fields.
In your case, Emp# and Raise-Date together might form the primary key.
EDIT At the logical level, those two fields form a compound primary key. That primary key indentifies uniquely each row of the table (unless an employee can have multiple raises per day) and is irreducible because none of those fields alone is sufficient to uniquely identify your records.
When you get to the physical level, you might want to introduce a surrogate primary Key (an ID) and create a unique index on the two columns (RaiseDate, Emp#).
You can find more information about the benefits and drawbacks of this approach here.