Path 'C:\Python32\lib\site-packages' is added to sys.path by the built-in site module.
If you want to, you can start python with the -S flag to tell the site module "Don't add site-packages".
python -S
Next, 'C:\python32\Lib\site-packages\django'.
Here's a wild guess: you installed django with pip/easy_install/msi-installer and there is a file
C:\python32\Lib\site-packages\django.pth (or something like this ending with .pth)
Quoting the docs:
A path configuration file is a file whose name has the form name.pth
and exists in one of the four directories mentioned above; its
contents are additional items (one per line) to be added to sys.path.
You can remove django.pth file (not recommended, see below) to remove '..../django' from sys.path
So, short answer: don't mess with sys.path, what's in sys.path is probably for a good reason.
If you don't need django, then uninstall django using whatever tool you used to install it. Same for every package you don't need.