I hope to help you out,
you will need several things
the line for filtering in the column of your choice...(i recommend you create a new attribute for this, ask me in comments if you want to know more why.) this goes in the cgridview of course:
'filter'=>CHtml::activeCheckBox($model, $attributeEmail)
the condition in your search of function that brings up the model.
Supposing you have a criteria inside your search in your model wich help you with your filtering what you need is ...
if($this->EMAIL == TRUE)
{
$criteria->addCondition("\"t\".\"EMAIL\" email NOT LIKE '%_@__%.__%'");
}
Why not to use regex and make a KISS approach ? better read this first...
Sql script to find invalid email addresses
I'd be glad to hear your comments it is interesting question for yii dev's btw