It works perfectly. I have tested it on Oracle 12c.
Update
I have checked My Oracle Support(Metalink), however, did not find anything related to this function returning NULL. Certainly, not a bug.
Anyway, looking deeper into the function and it's usage in the documentation, I came across SQLNET.CRYPTO_SEED
SQLNET.CRYPTO_SEED
Purpose
Use the parameter SQLNET.CRYPTO_SEED to specify the characters used
when generating cryptographic keys. The more random the characters
are, the stronger the keys are. The string should be 10-70 random
characters. This optional parameter is required for when encryption or
checksumming are turned on. Encryption is turned on if the
SQLNET.ENCRYPTION_CLIENT parameter is specified for the client and the
SQLNET.ENCRYPTION_SERVER parameter is specified for the database
server; checksumming is turned on if the SQLNET.CRYPTO_CHECKSUM_CLIENT
parameter is specified for the client and the
SQLNET.CRYPTO_CHECKSUM_SERVER parameter is specified for the database
server.
It might be possible that the parameter is not properly set in your environment. I don't have 10g version(obsolete though) to test.
Connected to:
Oracle Database 12c Enterprise Edition Release 12.1.0.1.0 - 64bit Production
With the Partitioning, OLAP, Advanced Analytics and Real Application Testing option
SQL> select DBMS_CRYPTO.RANDOMBYTES(64) from dual;
DBMS_CRYPTO.RANDOMBYTES(64)
--------------------------------------------------------------------------------
427AECD44D27CDF6CDC8F290D9F8079109BAB8AECD7E687E7ADF8E15825BBDF3D746FBC181059443
965B1425B224CC46E8CD07CC2D02B2E023238E8883520A19
SQL>