In 4 bit 2'scomplement -2 is 1110 and +3 is 0011 so
11110 carry
1110 -2
+0011 +3
----
10001 which is 0001 or simply 1 ignoring the carry in bit 5
Stepping through the process from the right to the left:
1 + 0 results in 1 with no carry
1 + 1 results in 0 with a carry of 1
1 + 0 + the carry of 1 results 0 with a carry of 1
1 + 0 + the carry of 1 results in 0 with a carry of 1
just the carry of 1 results in 1 with nothing more to carry
For reference see the Wikipedia article on 2's complement particularly the section on addition at https://en.wikipedia.org/wiki/Two%27s_complement#Addition. There are a number of online 2's complement calculators to help with conversions and one of them is at http://www.exploringbinary.com/twos-complement-converter/
Let me know if you want to see how -3 + -3 is done, since that is what you attempted. It is a similar process, but be sure start with bit length large enough to avoid overflow as determined when the leftmost two bits in the carry row have different values.