This worked for me using Chrome 62.0.3202.94, ChromeDriver 2.33.506120, Selenium 3.4.3, and Python 2.7.14 or 3.6.3, on Windows 7 x64:
import json
from selenium import webdriver
appState = {
"recentDestinations": [
{
"id": "Save as PDF",
"origin": "local",
"account": ""
}
],
"selectedDestinationId": "Save as PDF",
"version": 2
}
profile = {'printing.print_preview_sticky_settings.appState': json.dumps(appState)}
chrome_options = webdriver.ChromeOptions()
chrome_options.add_experimental_option('prefs', profile)
chrome_options.add_argument('--kiosk-printing')
driver = webdriver.Chrome(chrome_options=chrome_options)
driver.get('https://www.google.com/')
driver.execute_script('window.print();')