Sorry but you should use applicationWillTerminate
:
This method lets your app know that it is about to be terminated and
purged from memory entirely. You should use this method to perform any
final clean-up tasks for your app, such as freeing shared resources,
saving user data, and invalidating timers. Your implementation of this
method has approximately five seconds to perform any tasks and return.
If the method does not return before time expires, the system may kill
the process altogether.
For apps that do not support background execution or are linked
against iOS 3.x or earlier, this method is always called when the user
quits the app. For apps that support background execution, this method
is generally not called when the user quits the app because the app
simply moves to the background in that case. However, this method may
be called in situations where the app is running in the background
(not suspended) and the system needs to terminate it for some reason.
So if you need to save data ALSO when user manually kill the app use applicationDidEnterBackground
that it's called if your app support background mode.