Sending X-UA-Compatible HTTP Header or use a META tag in your page's HEAD will kick IE into a compatibility mode. So not doing so will let it run in normal mode.
If you want to test if the browser is compatible I would write an jQuery AJAX call that tries to use a javascript function that isn't working in older IE inside a try catch and POST the result to your application.
for example trim() doesn't work in IE8
var str = " Hello World! ";
var a = (str.trim());
if(a == "Hello World!"){
//Ajax Post true
} else {
//Ajax Post false
}
This should work because if enterprise mode is activated it will work inside IE8
http://blogs.msdn.com/b/ie/archive/2015/03/02/making-it-easier-for-enterprise-customers-to-upgrade-to-internet-explorer-11-and-windows-10.aspx