See this answer as to why there can't be a general toJSON case for Maps, and for similar reasons, Sets. Basically, keys and/or Set items can be anything, including objects and references to other things that can't be serialized into JSON (which, remember, is a specific format with specific, stricter rules than just "turn into intelligible data of another type"). What you want here is more like "toArray" anyhow. You method already works for that inline, as would Array.from(Set), I think.
But if you wanted to add this sort of method to the prototype for your own internal usage without risking possible problems if a similar (but not identical) method is ever added, you could use a Symbol key'd prop.
var toArray = Symbol('toArray');
Object.defineProperty(Set.prototype, toArray, {
enumerable: false,
value: function () {
return [...this];
}
});
var g = new Set();
g.add(9);
g[toArray]();//-> [9]
If you do that, then you are guaranteed to not cause problems with anything other than your own code, since only your code will have access to the toArray Symbol key that references that method.