With all non-trivial OS, process resources are reclaimed by the OS upon process termination.
Unless there is specifc and overriding reason to explicitly free memory upon termination, you don't need to do it and you should not try for at least these reasons:
1) You would need to write code to do it, and test it, and debug it. Why do this, if the OS can do it? It's not just redundant, it reduces quality because your explict resource-releasing will never get as much testing as the OS has already had before it got released.
2) With a complex app, with a GUI and many subsystems and threads, cleanly freeing memory on shutdown is nigh-on impossible anyway, which leads to:
3) Many library developers have already given up on the 'you must explicitly release blah... ' mantra because the complexity would result in the libs never being released. Many report unreleased, (but not lost), memory to valgrid and, with opaque libs, you can do nothing at all about it.
4) You must not free any memory that is in use by a running thread. To safely release all such memory in multithreaded apps, you must ensure that all process threads are stopped and cannot run again. User code does not have the tools to do this, the OS does. It is therefore not possible to explicitly free memory from user code in any kind of safe manner in such apps.
5) The OS can free off the process memory in big chunks - much more quickly than messing around with dozens of sub-allcations in the C manager.
6) If the process is being terminated because it has failed due to memory management issues, calling free() many more times is not going to help at all.
7) Many teachers and profs say that you must explicity free the memory, so it's obviously a bad plan.