Certificate chain is intermediate certificates(中级证书)
For Certificate chain, type or paste the PEM-formatted intermediate certificates and, optionally, the root certificate, one after the other without any blank lines. If you include the root certificate, your certificate chain must start with intermediate certificates and end with the root certificate. Use the intermediate certificates provided by your certificate authority. Do not include any intermediaries that are not in the chain of trust path. The following shows an abbreviated example.
-----BEGIN CERTIFICATE-----
EXAMPLECA4ugAwIBAgIQWrYdrB5NogYUx1U9Pamy3DANBgkqhkiG9w0BAQUFADCB
...
8/ifBlIK3se2e4/hEfcEejX/arxbx1BJCHBvlEPNnsdw8EXAMPLE
-----END CERTIFICATE-----
Here is another example.
-----BEGIN CERTIFICATE-----
Intermediate certificate 2
-----END CERTIFICATE-----
-----BEGIN CERTIFICATE-----
Intermediate certificate 1
-----END CERTIFICATE-----
-----BEGIN CERTIFICATE-----
Optional: Root certificate
-----END CERTIFICATE-----
For more details check amazon developer guide