First Of all I suggest you not to use CTE use temp table for your solution
use the below link for finding why I ma saying this
https://dba.stackexchange.com/questions/13112/whats-the-difference-between-a-cte-and-a-temp-table
to know more use the below link
http://www.dotnet-tricks.com/Tutorial/sqlserver/X517150913-Difference-between-CTE-and-Temp-Table-and-Table-Variable.html
Now lets us get back to your solution, i have used Temp Table
Select e.emp_num,e.from_date,e.to_date,e.[ req_ser],e.[ req_year],COUNT(1) number_of_duplicates
into #temp1 from empmission e
group by emp_num,from_date,to_date,[ req_ser],[ req_year]
Truncate Table empmission
Insert into empmission
Select t.emp_num,
t.from_date,
t.to_date,
t.[ req_ser],
t.[ req_year]
from #temp1 t
Drop Table #temp1 --Droping the temp table
Select * from empmission
Or You can go with CTE
As
WITH todelete As (
select em.*,
row_number() over (partition by emp_num, [from_date],[to_date],[ req_ser], [ req_year]
order by (select null)) as cnt
from empmission em
)
DELETE FROM todelete
WHERE cnt > 1;