First you should validate that Python is installed. You said it was installed here for your machine: C:\Users\Chaos\AppData\Local\Programs\Python\Python35-32\python.exe
You should double check that Python is in your system environment variables. This varies by version of windows but you essentially want to:
- go to control panel
- go to system
- go to advanced system settings
- click on environment variables
- Click on new or add and then add the path to the folder containing the python executable, so add this: C:\Users\Chaos\AppData\Local\Programs\Python\Python35-32\
Now launch cmd.exe and type in 'python' without the quotes and you should see the REPL launch. If the REPL doesn't launch you know you have an installation issue or didn't properly setup the environment variable. If the REPL does launch then you should be able to launch your python script from the command line:
python -m yourHelloWorld.py
Please note that you need to prove an absolute path to your file if it's not in the current working directory that you're trying to launch from, or you need to navigate to that directory.