Yes there is, and the necessary tool is included with VS.
Open the "Visual Studio Command Prompt (2010)" console from the start menu, and CD into C:\Program Files\Microsoft Visual Studio 10.0\Common7\IDE
(adjust for your own system if you have changed the installation directory or run 64-bit Windows).
Then do:
dumpbin /headers devenv.exe | more
The start of the output on my machine is:
Dump of file devenv.exe
PE signature found
File Type: EXECUTABLE IMAGE
FILE HEADER VALUES
14C machine (x86)
4 number of sections
4BA1FAB3 time date stamp Thu Mar 18 12:04:35 2010
0 file pointer to symbol table
0 number of symbols
E0 size of optional header
122 characteristics
Executable
Application can handle large (>2GB) addresses
32 bit word machine
The second to last line is what you are looking for -- if it's there, your executable is large address aware.