JIT Version
You can follow Hans' steps to verify that RyuJIT is loaded into your application. [2]
use the debugger to ensure you have the new version. First have a look-see at the runtime directory with Explorer, navigate to C:\Windows\Microsoft.NET\Framework64\v4.0.30319. You'll find the the two jitters there, clrjit.dll is new jitter based on the Ryujit project and compatjit.dll is the legacy x64 jitter.
Project > Properties > Debug > tick the "Enable native code debugging option". Use the Build tab and ensure you've removed the jitter forcing, the "Prefer 32-bit" option must be unticked, "Platform target" must be set to AnyCPU. And use the Application tab to pick the framework target.
Use Debug > Step Into to start debugging. Debug > Windows > Modules displays the list of loaded modules. Find the jitter DLLs back in that list, click the "Name" column header to sort by name. If you see compatjit.dll back then you are using the legacy jitter. Do note that you'll always see clrjit.dll, they both get loaded when the legacy jitter is used.
[2] https://stackoverflow.com/a/31534544/102351
JIT Architecture
You can determine the architecture of the JIT used by checking whether the running application is a 64-bit process or not.
Environment.Is64BitProcess
https://msdn.microsoft.com/en-us/library/system.environment.is64bitprocess.aspx
This property is implemented as a direct true/false return within the 64-bit and 32-bit versions of mscorlib, respectively. [1]
[1] https://stackoverflow.com/a/1913908