Since you tagged your question with the python
tag, I assume you are ok with using Python.
A possible solution is to read the content of each file and then produce a batch file that would execute xcopy
with each pair of file names. That file can be saved as a regular batch file and later executed:
infile1 = open("src.txt")
infile2 = open("dest.txt")
outfile = open("copyall.bat", "w")
# Assume the number of lines in both files is the same!
for src in infile1:
src = src.strip().replace(r'"',r'\"')
dest = infile2.readline().strip().replace(r'"',r'\"')
command = '''xcopy "%s" "%s"\n''' % (src, dest)
outfile.write(command)
outfile.close()
After you prepare the batch file, make sure to have a look into it before executing it! The first line of the file should look something like this:
xcopy "N:\PRS\CVs\Original CVs\2008***, *** Orig CV Aug 08.doc" "E:TRIS\Documents\Candidate\Original Resumes\N\***, ***Orig CV Aug 08.doc"