While I agree with scebotari's answer that in your case embedding a form in the toolbar is probably the easiest solution, for the sake of answering the original question:
If you really cannot or do not want to use a form and you're not limited regarding browser support, have a look at the FileReader.
The idea is to read the file contents on the client side (JavaScript) and then send the data using a regular AJAX request.
Your code could look like that:
function (fileField) {
var file = fileField.fileInputEl.dom.files[0],
reader;
if (file === undefined || !(file instanceof File)) {
return;
}
reader = new FileReader();
reader.onloadend = function (event) {
var binaryString = '',
bytes = new Uint8Array(event.target.result),
length = bytes.byteLength,
i,
base64String;
// convert to binary string
for (i = 0; i < length; i++) {
binaryString += String.fromCharCode(bytes[i]);
}
// convert to base64
base64String = btoa(binaryString);
Ext.Ajax.request({
url: 'save-file.php',
method: 'POST',
params: {
data: base64String
}
});
};
reader.readAsArrayBuffer(file);
}